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The pyrolysis of azetidine: Shock-tube kinetics similarities and contrasts with two analogs

✍ Scribed by Y-X. Zhang; C-L. Yu; S. H. Bauer

Publisher: John Wiley and Sons
Year: 1998
Tongue: English
Weight: 150 KB
Volume: 30
Category: Article
ISSN: 0538-8066
DOI: 10.1002/(sici)1097-4601(1998)30:3<185::aid-kin3>3.0.co;2-o

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✦ Synopsis

The kinetics of decomposition of azetidine {(CH 2 ) 3 N9 H)} was measured using single-pulse shock-tube techniques, over the temperature range in high argon 855-1100 K, dilution. These data confirm and extend an earlier investigation that utilized the very lowpressure pyrolysis method. A brief survey of many reports regarding the interesting features of azetidine is presented. In two appendices the thermodynamic and kinetic data on trimethylene sulfide, oxide, and immine are intercompared. New ab-initio calculations are cited for the parent species and their fragmentation products.