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The Pyrolysis of Allyl 2,4,6-Trialkylphenyl Ethers

✍ Scribed by Hurd, Charles D.; Yarnall, Willis A.

Book ID
125974064
Publisher
American Chemical Society
Year
1937
Tongue
English
Weight
505 KB
Volume
59
Category
Article
ISSN
0002-7863

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## 2,4,6-Trialkylphenylphospholes 3a (R‫ס‬Me), 3b (R‫ס‬i-Pr) and 3c (R‫ס‬t-Bu), with increasing flattening at phosphorus and hence with increasing electron delocalisation, underwent the Diels-Alder reaction with N-phenylmaleimide to give predominantly cycloadducts 4a-c with the trialkylphenyl subs