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The pyrogenic rearrangement of 3-(2-pyridyl)-pyrrole

โœ Scribed by A. G. Oosterhuis; J. P. Wibaut

Book ID
104585886
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
102 KB
Volume
55
Category
Article
ISSN
0165-0513

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The reaction of 2,3-di-(3-pyridyl)-2,3-butanediol (1) in H 2 SO 4 was studied. It was found that the meso and racemic forms give mono-and bis-SO 3 addition products, which rearrange to a ketone (Metopirone ยฎ ) and two other major by-products. The formation of SO 3 addition products and a marked incr