The pseudophase model of micellar catalysis. Addition of cyanide ion to N-alkylpyridinium ions
β Scribed by Bunton, Clifford A.; Romsted, Laurence S.; Thamavit, Chirasarit
- Book ID
- 127195956
- Publisher
- American Chemical Society
- Year
- 1980
- Tongue
- English
- Weight
- 522 KB
- Volume
- 102
- Category
- Article
- ISSN
- 0002-7863
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## Abstract The waterβsoluble poly(1βvinylβ2βethylimidazole) quaternized with ethyl bromide and lauryl bromide was prepared; lauryl group content, 8.8 mol% (Lβ9), 28.9 mol% (Lβ29), and 40.9 mol% (Lβ41). The Ξ»~max~ value of methyl orange near 460 nm shifted to shorter wavelengths (417β433 nm) in the
Steady-state and time-resolved fluorescence quenching techniques were used to study the interaction of short-chain Nalkylpyridinium ions with sodium dodecyl sulfate (SDS) micelles using pyrene as a probe. The rate constants of the quenching of pyrene and binding constants of the cations to SDS micel