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The protonation of conjugated enolic derivatives: Part III

✍ Scribed by T.N. Huckerby; N.A.J. Rogers; A. Sattar

Book ID
104223787
Publisher
Elsevier Science
Year
1967
Tongue
French
Weight
218 KB
Volume
8
Category
Article
ISSN
0040-4039

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✦ Synopsis

In previous communications1 we have described the pattern of kinetically controlled protonation in a series of alkyl-substituted, conjugated dienolic ethers.

In the cisoid series, a rough linear relationship between log ka/ku and (qa -qY), the calculated charge density difference between the a-and y-carbon atoms was established. i.e. & log k = A.&q + B . . ..*.......

πŸ“œ SIMILAR VOLUMES

The protonation of conjugated enolic der
The protonation of conjugated enolic derivatives. Part II.
✍ N.A.J. Rogers; A. Sattar πŸ“‚ Article πŸ“… 1965 πŸ› Elsevier Science 🌐 French βš– 179 KB

In an earlier Oommunioation (1) it was demonstrated that under kinetically controlled conditions, proton&ion of the homoannular, conjugated dienol ether (I) et the a-and yosrbon atoms were competitive processes. In the same paper