The proton potential in short hydrogen bonds
✍ Scribed by D. Hadži
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 814 KB
- Volume
- 100
- Category
- Article
- ISSN
- 0022-2860
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
2%~ diffcrcncc in chemicnt shift between hydrogen bonded protons and deutcrons has been cxzmincd bodr tlworetitally nnd cxpcrimcntaliy. it is shown that valuable information about the hydrogen bond poteM can bc cxtmcted from this isotope effect on chcmicd rhifts.
The energy levels and wavefunctions of the protons of the hydrogen bonds in DNA base pairs are numerically wlculated for a s&es of adiabatic potential awes. The phenomenon of the swxlled proton tunnelling is discussed.
Dedicated to Professor Michele Parrinello on the occasion of his 60th birthday.