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The Properties of a Ferrocene-Tetracyanoethylene Charge-Transfer Complex

✍ Scribed by Rosenblum, M.; Fish, R. W.; Bennett, C.


Book ID
121229782
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
665 KB
Volume
86
Category
Article
ISSN
0002-7863

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## Abstract Arylazoaminopyrazoles (1a–d) reacts with tetracyanoethylene (TCNE) to yield pyrazolo[1,5‐a]pyrimidines (9) via charge‐transfer (CT) complex formation. The effect of the substituents on the basicity of the pyrazole nucleus as well as the complexation centre in different types of pyrazole