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The Production of a Poison for Nickel Catalysts in the Absorption of Oxygen by Fieser's Solution 1

โœ Scribed by Burford, W. B.; Frazer, J. C. W.

Book ID
126216481
Publisher
American Chemical Society
Year
1945
Tongue
English
Weight
278 KB
Volume
67
Category
Article
ISSN
0002-7863

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The interaction of the olefin oligomerization catalyst system derived from [Ni(sacsac)(PBu,)CI] (sacsac = pentane-2,4-dithionate = dithioacetylacetonate) with carbon monoxide (CO) has been examined by a combination of ,'P NMR and FTIR spectroscopy. The catalyst is rapidly and completely inhibited by