The principle of corresponding states and the dynamic properties of simple liquids
โ Scribed by Jacques Rouch; Jean-Pierre Boon; Paul A. Fleury
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 577 KB
- Volume
- 88
- Category
- Article
- ISSN
- 0378-4371
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โฆ Synopsis
We present a corresponding states analysis of existing data on sound velocity, transport coefficients and intermolecular interaction times of a number of simple fluids. With appropriate choices of parameters for the intermolecular pair potential, such properties as the adiabatic sound velocity, the shear and bulk viscosities, the thermal conductivity and the intermolecular interaction time can be reduced along the liquid-vapor equilibrium curve. Deviations from the simple law of corresponding states are most pronounced for the transport properties, indicating a stronger sensitivity of the dynamical properties to the interaction potential and the molecular structure.
๐ SIMILAR VOLUMES
Experimental surface-tension data for pure substances have been correlated successfully by the use of two recent modifications of the principle of corresponding states. The results are expressed in terms of simple analytical relations which allow one to calculate the surface-tension curves either fr