The Primary Product of the Synthesis of Ascorbic Acid and its Analogues. Observations complementary to the preceding paper
β Scribed by W. N. Haworth; E. L. Hirst
- Publisher
- John Wiley and Sons
- Year
- 1934
- Tongue
- German
- Weight
- 275 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0018-019X
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β¦ Synopsis
dcctonz;erbindzing des l-Ascorbinsuzirc-3-methylathei~s. 0,3 g Aceton-I-ascorbinsaure tvurclen wie oben methyliert. Das Rohproclukt erstarrte sehr rasch, als die Losung desselben in wenig absolutem Ather mit etwas Pentzln versetzt angerieben wurde. Aus iither-Pentan farblose Krystallblattchen, Smp. 88-90 a-[XI::" = ca. + 20" (c = 1,235 in Methanol niit nicht ganz reiner Probe gemrssen).
π SIMILAR VOLUMES
Selective Oxidation of Primary Silyl Ethers and Its Application to the Synthesis of Natural Products. -The direct oxidation of primary Tms and Tes ethers in the presence of various functional groups including secondary silyl ethers selectively yields the aldehydes (II) as useful intermediates for l
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