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The preparation, structures and reactivity of complexes with molybdenum-nitrogen multiple bonds

✍ Scribed by M.W Bishop; J Chatt; J.R Dilworth; M.B Hursthouse; M Motevalle

Book ID
116012862
Publisher
Elsevier Science
Year
1977
Weight
409 KB
Volume
54
Category
Article
ISSN
0022-5088

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Molybdenum Amido Complexes with Single M
Molybdenum Amido Complexes with Single MoN Bonds: Synthesis, Structure, and Reactivity
✍ Dolores Morales; Julio PΓ©rez; LucΓ­a Riera; VΓ­ctor Riera; Daniel Miguel; Marta E. πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 English βš– 369 KB πŸ‘ 1 views

Reactions of the complex [MoCl(eta(3)-C(3)H(4)-Me-2)(CO)(2)(phen)] (1) (phen=1,10-phenanthroline) with potassium arylamides were used to synthesize the amido complexes [Mo(N(R)Ar)(eta(3)-C(3)H(4)-Me-2)(CO)(2)(phen)] (R=H, Ar=Ph, 2 a; R=H, Ar=p-tolyl, 2 b; R=Me, Ar=Ph; 2 c). For 2 b the Mo-N(amido) b