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The Preparation of Unsymmetrical Secondary Aliphatic Amines 1

✍ Scribed by Campbell, Kenneth N.; Sommers, Armiger H.; Campbell, Barbara K.


Book ID
120436043
Publisher
American Chemical Society
Year
1944
Tongue
English
Weight
400 KB
Volume
66
Category
Article
ISSN
0002-7863

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Polystyrene sulfonic acid esters as alky
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Spherical beads (210-290 w) of styrene-divinyl benzene (10%) copolymer have been chlorosulfonated and reacted with alcohols to give corresponding sulfonate esters. Their reactions with primary amines, i.e. propyl amine and aniline, give the corresponding secondary amines in reasonable yields (67-76%