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The Preparation of Pyrrole-2-carboxylates From Vinyl Sulfones

✍ Scribed by Arnold, DP; Burgessdean, L; Hubbard, J; Rahman, MA

Book ID
127183303
Publisher
Commonwealth Scientific and Industrial Research Organisation Publishing
Year
1994
Tongue
English
Weight
306 KB
Volume
47
Category
Article
ISSN
0004-9425

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Deiodination of 5-iodopyrrole-2-carboxyl
Deiodination of 5-iodopyrrole-2-carboxylates using sodium formate catalyzed by palladium complexes: preparation of 5-unsubstituted pyrrole-2-carboxylates
✍ Sam H. Leung; Daniel G. Edington; Tara E. Griffith; Jammie J. James πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 173 KB

5-Iodopyrrole-2-carboxylates are deiodinated with sodium formate in the presence of a catalytic amount of either PdC12(Ph3P)2 or Pd(Ph3P)4 to give the corresponding 5-unsubstituted pyrrole-2-carboxylates in good yields.