The preparation of phenylglycine-o-carboxylic acid. I. From anthranilic acid and monochloracetic acid
β Scribed by Herbert L. Haller
- Publisher
- Elsevier Science
- Year
- 1923
- Tongue
- English
- Weight
- 53 KB
- Volume
- 195
- Category
- Article
- ISSN
- 0016-0032
No coin nor oath required. For personal study only.
β¦ Synopsis
A =ETI-IOD has been developed by which anthraquinone may be determined quantitatively in mixtures containing also phenanthraquinone, anthracene, phenanthrene, phthalic anhydride, phthalic acid, or other oxidation products of anthracene or phenanthrene. It consists essentially in reducing the anthraquinone to the red oxanthranol, using zinc powder and 5 per cent. solution of sodium hydroxide. The red solution is filtered in vacuum and titrated with standard potassium permanganate.
π SIMILAR VOLUMES
FANTONI\* a n d T.TORROBAa C e n t r o d i S t u d i o d e l C . N . R . s u l l a C h i m i c a e l a S t r u t t u r a d e i C o m p o s t i E t e r o c i c l i c i e l o r o A p p l i c a z i o n e , c / o D i p a r t i m e n t o d i C h i m i c a O r g a n i c a " U . S c h i f f " , V i a G . C
An efficient and practical synthesis of 3-substituted quinazolinediones is described. The protocol uses readily available isocyanates and anthranilic acids as precursors in a one-pot operation and has been demonstrated on >50 g scale. Isolation of the products via filtration directly from the reacti