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The preparation of N-(alkyl and arylsulfinyl)-phthalimides. A new class of sulfinyl-transfer reagents1

✍ Scribed by David N. Harpp; Thomas G. Back

Book ID: 104237042
Publisher: Elsevier Science
Year: 1972
Tongue: French
Weight: 187 KB
Volume: 13
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)85238-2

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✦ Synopsis

It has recently been found that alkyl and arylthioimides 1 act as efficient sulfurtransfer agents.

They react with thiols2anbVc, hydrodisulfideseb, alkoxides3, amines4, and arenesulfinates5 to give disulfides, trisulfides, sulfenate esters, sulfenamides and thiolsulfonates respectively. Moreover, N,N'-thiobisphthalimide (2) generates N,N'-thiobisamines

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