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The Preparation of Hydroxypyrazines and Derived Chloropyrazines

✍ Scribed by Karmas, George; Spoerri, Paul E.


Book ID
118130608
Publisher
American Chemical Society
Year
1952
Tongue
English
Weight
688 KB
Volume
74
Category
Article
ISSN
0002-7863

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## Abstract ^1^H, ^13^C, ^14^N and ^15^N NMR chemical shifts were used to prove the structures of the products of 2‐chloropyrazine oxidation. It was shown that oxidation by hydrogen peroxide in acetic acid or __m__‐chloroperbenzoic acid leads to the __N__4‐oxide, whereas potassium persulfate in sul