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The preparation of different types of polynuclear transition metal sulfur compounds by thiometallates, including cubane-like ones. Crystal structures of {Cu3WS3Cl}(PPh3)3S, {Cu3WS3Cl}(PPh3)3O, {Cu3MoS3Cl}(PPh3)3S, {Cu3MoS3Cl}(PPh33O, (PPh3)3Cu2WS4·0.8CH2Cl2 and (PPh3)3Ag2MoS4·0.8CH2Cl2

✍ Scribed by Achim Müller; Harmut Bögge; Uwe Schimanski

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