The preparation of derivatives of 2,2′-(2,6-naphthalenediylidene)bis(1,3-dithiole) (nbdt): New donors for organic metals
✍ Scribed by Martin R. Bryce
- Book ID
- 104232712
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- French
- Weight
- 154 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
4,5-(Methoxymethylenedithio)-l,3-dithiole-2-chalcogenones 3 and 4 have been alkylated by using R3AI and RMgX (X = CI or Br)/TiCI4 complex reagent to give the title compounds 1 and 2. Cross-coupling of la--d with 5 furnished the mono-alkylated MET derivatives 6a--d, and the CIO 4 and PF 6 salts of 6b
## Abstract A series of N‐N‐N terdendate polypyridine type ligands and their N‐C‐N cyclometalating homologues were synthetized and fully characterized (L~1~‐L~12~). Complete assignments of the ^1^H spectra of the various compounds, accomplished by using a combination of one‐ and two‐dimensional nmr