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THE PREPARATION OF CYCLOBUTANE

✍ Scribed by CASON, JAMES; WAY, RICHARD L.


Book ID
125859198
Publisher
American Chemical Society
Year
1949
Tongue
English
Weight
439 KB
Volume
14
Category
Article
ISSN
0022-3263

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Hydrated oxocarbons, I. Preparation and
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Octahydroxycyclobutane (1) reacts with various monoorganoboranes to give in high yields the tetrakis[organoboranediylbis(oxy)] derivatives 2a -d. These react with tertiary amines to yield either 1 : 2 or 1 : 4 adducts. Depending on the organo substituents at the boron atoms, alcoholyses of 2a -d res