The Preparation of 1,5-Anhydro-D-mannitol (Styracitol) from D-Mannitol
โ Scribed by Fletcher, Hewitt G.; Diehl, Harry W.
- Book ID
- 121424293
- Publisher
- American Chemical Society
- Year
- 1952
- Tongue
- English
- Weight
- 286 KB
- Volume
- 74
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## D-Mannitol (1) was converted into 1,5-anhydro-r~-mannitol, which was treated consecutively with p-toluenesulfonyl chloride (1 mol. equiv.) and benzoyl chloride (3 mol. equiv.), to produce 1,5-anhydro-2,3,4-tri-0-benzoyl-6-O-p-tolylsulfonyl-D-mannitol. 1,5-Anhydro-2,3,4-tri-O-benzoyl-6-deoxy-6-
2,5-Anhydro-1-O-(p-tolylsulfonyl)-D-mannitol, C13H18SO7, Mr = 318.4, monoclinic, C2, a = 26.370(6), b = 7.9741(11), c = 6.6801(6) A, beta = 91.401(11) degrees, V = 1404.3(6) A3, Z = 4, DX = 1.506 g/cm3, CuK alpha, lambda = 1.54184 A, mu = 23.03 cm-1, F(000) = 672, T = 296(1) K, R = 0.042 for 2832 ob