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The Preparation of 1-Carboxy-4-substituted Bicyclo[2.2.2]octanes

✍ Scribed by Holtz, Hans D.; Stock, Leon M.


Book ID
121358169
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
826 KB
Volume
86
Category
Article
ISSN
0002-7863

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NMR Study of Substituted Bicyclo[3.2.1]o
✍ John W. Blunt; Andrew Burritt; James M. Coxon; Peter J. Steel πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 455 KB πŸ‘ 1 views

The 'H and I3C NMR spectra of six bromo-and methoxybicyclo[3.2.1]octanes were completely assigned. An axial bromine substituent at C-2 or C-4 results in a 5 ppm upfield shift of C-8 due to the gauche interaction. An equatorial bromine results in an upfield shift of similar magnitude on either C-6 (o