✦ LIBER ✦

The preparation and structure of 1,4,5,6,7,7-hexachloro-2-endo-ferrocenylhydroxymethyl-3-endo-hydroxymethyl-5-norbornene

✍ Scribed by P Carty; J Grant; E Metcalfe; D C Povey

Publisher: John Wiley and Sons
Year: 1989
Tongue: English
Weight: 397 KB
Volume: 3
Category: Article
ISSN: 0268-2605
DOI: 10.1002/aoc.590030212

No coin nor oath required. For personal study only.

✦ Synopsis

The crystal structure of a novel ferrocene derivative with potential flame-retardanthmoke-suppressant activity, 1,4,5,6,7,7-hexachloro-2-endo-ferrocenylhydroxymethyl-3-endo-hydroxymethyl-5-norbornene, has been determined. Some of the carbon-carbon bonds within the chlorendic residue are unusually long, and there is no interaction between the hydroxyl groups and the iron atom. There is evidence of intramolecular hydrogen bonding between the two hydroxyl groups.

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