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The Preparation and Reactions of Some 7-Silanorbornadienes. I. An Approach to Dimethylsilylene

โœ Scribed by Gilman, Henry.; Cottis, Steve Gust.; Atwell, William H.


Book ID
127179476
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
537 KB
Volume
86
Category
Article
ISSN
0002-7863

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The reactions of dimethylsilylene, SiMez, generated by laser flash photolysis from pentamethyldisilane and octamethyltrisilane, and detected via its 457.9 nm absorption, have been investigated with a number of oxygen containing molecules, including oxygen itself, carbon monoxide, water, alcohols, an