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The preparation and racemization of an optically active sulfonium ylide. (-)-Ethylmethylsulfonium phenacylide

โœ Scribed by Darwish, David.; Tomilson, Ralph L.


Book ID
125434292
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
292 KB
Volume
90
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES


The preparation and racemization of opti
โœ B.C. Menon; David Darwish ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 188 KB

We have reported previously that the optically active ylide ethylmethylsulfonium phenacylide 1 undergoes thermal racemization, through pyramidal inversion, faster than the corresponding sulfonium salts and the sulfoxides. ' The