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The preparation and properties of the acetate complex of trivalent cobalt

✍ Scribed by J. Buděšínský; J. Doležal; B. Šrámková; J. Zýka


Publisher
Elsevier Science
Year
1971
Tongue
English
Weight
639 KB
Volume
16
Category
Article
ISSN
0026-265X

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It is shown by EPR and magnetic susceptibility (x) measurements that acetate-N-methyl-octaethylporphyrinato-Co(I1) has a high-spin ground state. The complex in toluene gives EPR spectra with g= 4.4 and 2.04 and x with kn= 4.4 BM and Dz 20 cm-', which indicates square-pyramidal geometry around Co( II