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The preparation and analysis of the phenyldimethylsilyllithium reagent and its reaction with silyl enol ethers

✍ Scribed by Fleming, Ian; Roberts, Richard S.; Smith, Stephen C.

Book ID
111924576
Publisher
Royal Society of Chemistry
Year
1998
Weight
110 KB
Volume
7
Category
Article
ISSN
1472-7781

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The molecular mechanism of the domino reaction of nitroalkenes with silyl enol ethers to give nitroso acetal adducts was characterized using computational procedures at the PM3 semiempirical level. The domino process comprises three consecutive steps: the first and rate-determining step is the nucle