The preferred conformation of bicyclo[3,3,2]decane

✍ Scribed by Martin Doyle; Russell Hafter; William Parker

• Book ID: 104248243
• Publisher: Elsevier Science
• Year: 1971
• Tongue: French
• Weight: 279 KB
• Volume: 12
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(01)97340-x

✦ Synopsis

The preferred conformationa (1) and ( 2) have been aeeigmd2 to bicyclo[3,3,2] decant-g,iO-semi&one and bicyclo[3,2,~]nonan-6,7-semidione, on the basis of e.6.r. hyperfine splitting con&ante. Extrapolation of thie data led to the pro~oeal that bicyclob,3.2] decane itself preferred the be&-chair3 conformation (3(b)). %mmr. the tr8Mposition