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The ‘preference factor’ and isotope effect in the loss of hydrogen or deuterium from labeled toluenes

✍ Scribed by J. H. Beynon; J. E. Corn; W. E. Baitinger; R. M. Caprioli; R. A. Benkeser


Publisher
John Wiley and Sons
Year
1970
Tongue
English
Weight
346 KB
Volume
3
Category
Article
ISSN
1076-5174

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Preference factors and isotope effects i
✍ J. Van Thuijl; K. J. Klebe; J. J. Van Houte 📂 Article 📅 1971 🏛 John Wiley and Sons 🌐 English ⚖ 311 KB

The mass spectra of deuterated pyrazoles show that loss of H' and of HCN from the molecular ion occurs with a very high specificity from the 3(5)-position. For the two processes isotope effects and preference factors have been determined. Metastable ion decompositions involving the loss of HCN from