𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The prediction of the performance of packed-bed catalytic reactors in the air-oxidation of o-xylene

✍ Scribed by P.H. Calderbank; K. Chandrasekharan; C. Fumagalli

Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
805 KB
Volume
32
Category
Article
ISSN
0009-2509

No coin nor oath required. For personal study only.

✦ Synopsis

Absfract-The kmetlcs of the catalytic au-oxldatlon of o-xylene to phthahc anhydrIde over various commercial V,O, and T10rV205 catalysts are extended and a model derived which correctly predicts the temperature and yield profiles m a quasi-Isothermal fixed-bed reactor of commercial dlmenslons The model predicts the relative freedom from thermal "run-away" of commercial fixed-bed reactors and IS used to demonstrate the possrtuhtles of operation at elevated Xylene concentrations In what follows, XH, TA, PI and PA refer to o-xylene o-toluakdehyde, phthahde and phthabc anhydrlde respechvely, sometimes abbreviated to A, B, C and D

πŸ“œ SIMILAR VOLUMES

Kinetics of the catalytic air-oxidation
Kinetics of the catalytic air-oxidation of o-xylene measured in a tube-wall-catalytic reactor
✍ K. Chandrasekharan; P.H. Calderbank πŸ“‚ Article πŸ“… 1980 πŸ› Elsevier Science 🌐 English βš– 500 KB

The klnetlc parameters In a complex reaction network (oxldatlon of o-xylene over V205) were derived by multlresponse analysis of rate data from a tube-wall-catalytic reactor using two different catalysts The 2D model of thrs reactor was reduced to 1-D format by a systematic method of analysis which

Mathematical modelling of the exothermic
Mathematical modelling of the exothermic packed bed reactor: application to o-xylene partial oxidation
✍ D.L. Cresswell; W.R. Paterson πŸ“‚ Article πŸ“… 1970 πŸ› Elsevier Science 🌐 English βš– 759 KB

The influences of "in-pore" diffusion and film heat and mass transfer on catalyst effectiveness and selectivity are examined for a system of highly exothermic parallel and consecutive reactions, typified, for example, by the partial oxidation of o-oxylene to phthalic anhydride. Parametric sensitivit

Prediction of the performance of catalyt
Prediction of the performance of catalytic fixed bed reactors for Fischer-Tropsch Synthesis
✍ G. Bub; M. Baerns; B. BΓΌssemeier; C. Frohning πŸ“‚ Article πŸ“… 1980 πŸ› Elsevier Science 🌐 English βš– 552 KB

From kinetic measurements in a laboratory-scale recycle reactor product distributions for Fischer-Tropsch Synthesis in a fixed bed reactor are predrcted and compared with results from pilot plant experiments.