The potential of zero charge of jellium
โ Scribed by Wolfgang Schmickler
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 411 KB
- Volume
- 99
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
A model of the interface metal/electrolyte is presented in which the metal is represented as jellium. the solvent as an ensemble of dipoles. The potential of zero charge of the interface is calculated for various electronic densities of the jellium. The results are discussed with respect to experimental data.
๐ SIMILAR VOLUMES
In a positively charged metallic cluster, surface tension tends to enhance the ionic density with respect to its bulk value, while surface-charge repulsion tends to reduce it. Using the stabilized jellium model, we examine the self-expansion and compression of positively charged clusters of simply m
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A new apparatus for determination of potentials of zero charge by the immersion method is described. PZC values for Au, Cu, Fe and Ni have been determined by this means, and are compared with those reported in the literature.