The potential of composite pyrolysis gas chromatographic mass spectra in the study of lignocellulosics

✍ Scribed by James B. Reeves III; Guido C. Galletti

• Publisher: John Wiley and Sons
• Year: 1993
• Tongue: English
• Weight: 692 KB
• Volume: 28
• Category: Article
• ISSN: 1076-5174
• DOI: 10.1002/oms.1210280529

✦ Synopsis

The objective of this work was to evaluate the use of composite mass spectral (CMS) data from pyrolysis gas chromatopaphy/mass spectrometry (PY-GC/MS) for lignocellulosic materials. Various forages, by-products and fiber fractions derived from them were examined as CMS by PY-CC/MS. The PY-GC/MS system consisted of a heated platinum filament, a capillary gas chromatograph and an ion trap detector (ITD) mass spectrometer operated under electron impact conditions. Mass spectra were then composited in several ways by summing all the mass spectra acquired within retention times corresponding to major product classes. CMS data were entered in a dedicated library and compared using the ITD library editor software. The usefulness of such a simple procedure for studies related to lignocellulose analysis, such as forage recognition, development of analytical methods and digestibilitylmaturity correlation, is discussed.