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The potential curve for the C 1Π state of InCl

✍ Scribed by U. Wolf; E. Tiemann

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
461 KB
Volume
139
Category
Article
ISSN
0009-2614

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✦ Synopsis

The predissociation C 'II state of InCl was investigated by pulsed dye-laser radiation which excites the C 'II-X 'X + transition. Predissociation lifetimes of the order of picoseconds were determined by analysis of linewidths. For a quantitative description of the predissociation the semiclassical approximation for tunneling resonances was used. The potential curve of the C 'II state calculated from the measured data shows a very shallow minimum at small internuclear distance and a maximum at medium internuclear distance which is responsible for the predissociation. Vibrational levels v=O, 1,2 exist below the potential maximum.

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