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The possibility of initiating the chain oxidation of polymers by nitrogen oxide radicals

✍ Scribed by V.V. Guryanova; B.M. Kovarskaya; L.A. Krinitskaya; M.B. Neiman; E.G. Rozantsev


Book ID
118357209
Publisher
Elsevier Science
Year
1965
Weight
274 KB
Volume
7
Category
Article
ISSN
0032-3950

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The initiation of polystyrene photo-oxidation has been studied and the quantum yield of initiation (~PR') for u.v.-irradiation at 315 K in the presence of atmospheric oxygen has been found to be 10 -3. Using ESR spectra, five distinct free radicals have been found; their nature depends on the wave l