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The position of the phenolic function in tiliacorine and related alkaloids

โœ Scribed by Shamma, Maurice.; Foy, James E.; Govindachari, Tuticorin R.; Viswanathan, Narayana.


Book ID
126219757
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
308 KB
Volume
41
Category
Article
ISSN
0022-3263

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โœ Jan A. Glinskil; Leon H. Zalkow ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 257 KB

An efficient synthesis of heliotridine from readily available retronecine was accomplished by nucleophilic displacement of the 7-mesylate, in the 7-mesyl-Q-bentoate of retronecine with various cesium carboxylates in DMF, followed by hydrolysis. The synthetic procedure also permits the ready synthesi