The polymerization of cyclic phenylsesquisiloxanes
โ Scribed by K.A. Andrianov; G.A. Kurakov; F.F. Sushentsova; V.A. Myagkov; V.A. Avilov
- Book ID
- 118357373
- Publisher
- Elsevier Science
- Year
- 1965
- Weight
- 75 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0032-3950
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๐ SIMILAR VOLUMES
## Abstract **Summary:** The radical polymerization of different substituted methyl 2โ(bicyclo[3.1.0]hexโ1โyl) acrylates, **1a**โ**f**, was initiated by 2,2โฒโazoisobutyronitrile (AIBN) at 65โยฐC in chlorobenzene. The radical homopolymerization of **1a**โ**f** occurred through the opening of the cycl
## Abstract Methyl 2โ(bicyclo[3.1.0]hexโ1โyl)acrylate (**1**) was synthesized from methyl 2โ(cyclopenteneโ1โyl)โ2โhydroxyacetate by cyclopropanation, followed by oxidation to the corresponding bicyclic 2โoxoacetate and Wittig olefination with methyltriphenylphosphonium bromide. Initiated with 2,2โฒโ