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The polymerization of alkyl substituted acetylenes using metal halide based initiators: The bulky substituent effect

โœ Scribed by Jay Kunzler; Virgil Percec

Book ID
105014510
Publisher
Springer
Year
1992
Tongue
English
Weight
495 KB
Volume
29
Category
Article
ISSN
0170-0839

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๐Ÿ“œ SIMILAR VOLUMES

Living polymerization of aryl substitute
Living polymerization of aryl substituted acetylenes by MoCl5 and WCl6 based initiators: The ortho phenyl substituent effect
โœ Jay Kunzler; Virgil Percec ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 835 KB

## Abstract The polymerization of phenylacetylene initiated by MoCl~5~ and WCl~6~ based initiators was monitored directly in the NMR sample tube and demonstrated the presence of backbiting and intramolecular cyclization reactions. It was shown that the ratio of cis to trans structural units obtaine