The reduction of Bi(II1) to Bi(Hg) at the dropping mercury electrode in 0.5 M perchloric acid solution containing O-0.3 M chloride ion becomes increasingly reversible, generally speaking, as the [Cl-]/pi(III)] ratio increases, as evidenced by changes in various criteria used for determining the "rev
The polarographic behavior of nickel(II) in acetonitrile in the presence of chloride ion
β Scribed by Ivory V. Nelson; Reynold T. Iwamoto
- Publisher
- Elsevier
- Year
- 1963
- Weight
- 629 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0368-1874
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π SIMILAR VOLUMES
It is shown theoretically and experimentally that the first catalytic pre-wave in the Ni\*+-NCS-system (the reduction of the [Ni(NC%] complex) at COOS-< (l\*O-1.5) X IO-\* M (cNC#-> twin+) and within a wide range of ionic strength I can be described by a simplified kinetic equation based on the assu
The nature of polarographic precurrents o f nickel( 11) i o n i n the presence o f ampicillin as well ;IS the behavior of ampicillin in the electrical double layer lias been investigated, and the reduction mech:inism has been proposed. The rate o f the homogeneous c1iemic;il reaction w;is calculated