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The photosensitized rearrangement of benzobicyclo[2.2.2]octadienones

โœ Scribed by Harold Hart; Roger K. Murray Jr.

Publisher
Elsevier Science
Year
1969
Tongue
French
Weight
170 KB
Volume
10
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

While the most common photochemical transformation of medium-sized monocyclic S,y-unsaturated ketones involves a 1,3-acyl shift and migration of the allylic double bond,' 3-cyclohexenones such as t have been observed3 to photochemically rearrange with 1,2-acyl migration, to yield conjugated cyclopropyl ketones (2). The multiplicity of this photorearrangement has ?.

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