𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The photoproduction of dihydroxotetracyano-cobaltate(III)

✍ Scribed by L. Viaene; J. D'Olieslager; S. De Jaegere


Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
211 KB
Volume
83
Category
Article
ISSN
0037-9646

No coin nor oath required. For personal study only.

✦ Synopsis


A t 25'C a quantum y i e l d o f 0 . 0 9 3 was c a l c u l a t e d . The t h e r m a l a n a t i o n of cis-Co(CN),,(OH);w i t h CN-was found t o f o l l o w second o r d e r k i n e t i c s w i t h a r a t e c o n s t a n t k = 1.2.10-2 l.mole-' sec-' a t 25'C. ' To whom a l l m a i l s h o u l d be a d d r e s s e d .


πŸ“œ SIMILAR VOLUMES


The Reactivity of the Pentacyano(Ξ·1-Diox
✍ Michel H. Gubelmann; StΓ©phane Riittimann; Bernard Bocquet; Alan F. Williams πŸ“‚ Article πŸ“… 1990 πŸ› John Wiley and Sons 🌐 German βš– 556 KB

The mononuclear q l-dioxygen complex [CO(CN),O,]~-(A) decomposes in aqueous solution to the hydroxocomplex [Co(CN),OHI3-(B) and the hydroperoxo complex [Co(CN),O0Hl3-(C). The mechanism involves partial dissociation of A to give [CO(CN),]~-(E) which binds with unreacted A to give the q':ql-peroxo com