The photoproduction of dihydroxotetracyano-cobaltate(III)
β Scribed by L. Viaene; J. D'Olieslager; S. De Jaegere
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 211 KB
- Volume
- 83
- Category
- Article
- ISSN
- 0037-9646
No coin nor oath required. For personal study only.
β¦ Synopsis
A t 25'C a quantum y i e l d o f 0 . 0 9 3 was c a l c u l a t e d . The t h e r m a l a n a t i o n of cis-Co(CN),,(OH);w i t h CN-was found t o f o l l o w second o r d e r k i n e t i c s w i t h a r a t e c o n s t a n t k = 1.2.10-2 l.mole-' sec-' a t 25'C. ' To whom a l l m a i l s h o u l d be a d d r e s s e d .
π SIMILAR VOLUMES
The mononuclear q l-dioxygen complex [CO(CN),O,]~-(A) decomposes in aqueous solution to the hydroxocomplex [Co(CN),OHI3-(B) and the hydroperoxo complex [Co(CN),O0Hl3-(C). The mechanism involves partial dissociation of A to give [CO(CN),]~-(E) which binds with unreacted A to give the q':ql-peroxo com