The Photolysis of Ozone by Ultraviolet Radiation. III. The Photolysis of Dry Ozone/Oxygen Mixtures at Low Pressures in a Flow System

The chain mechanism of ozone destruction

The chain mechanism of ozone destruction by CFCl3 in the 214 nm photolysis of its mixtures with oxygen

✍ A. Horowitz; G. Schuster; G. K. Moortgat 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 740 KB

## Abstract The effect of CFCl~3~ (0.025–0.200 mbar) addition on the formation of ozone in 214 nm photolysis of oxygen (800–2000 mbar) was investigated. Kinetic analysis of the drastic reduction in ozone formation in the presence of CFCl~3~ shows that it proceeds by a chain mechanism with a chain l