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The photolysis of 1-azido-4-methylbicyclo[2.2.2]octane and 1-azidoadamantane in low-temperature matrices

✍ Scribed by Ian R. Dunkin; Charles J. Shields; Helmut Quast; Bernhard Seiferling

Book ID
104226429
Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
158 KB
Volume
24
Category
Article
ISSN
0040-4039

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Recently we reported a new method for the substitution of an hydroxy-or methoxy-group on the bridgehead carbon atom in the bicyclo[2.2.2]octane series by halogens (I), using various halogenating agents [e.g. POCl3, SOC12, PBr3 and also alkali chlorides, bromides or iodide8 (2)] in the presence of po