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The Photoelectron Spectra of Dimethoxysulfane and Dimethoxydisulfane

✍ Scribed by Gleiter, Rolf ;Hyla-Kryspin, Isabella ;Schmidt, Heinar ;Steudel, Ralf

Publisher
Wiley (John Wiley & Sons)
Year
1993
Tongue
English
Weight
279 KB
Volume
126
Category
Article
ISSN
0009-2940

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✦ Synopsis

Dimethoxysulfane / Dimethoxydisulfane / Photoelectron spectra / Calculations, MO / Ligand properties The He(1) photoelectron spectra of dimethoxysulfane (1) and dimethoxydisulfane (2) have been recorded. The lowest energy ionizations in the PE spectrum of 1 can be explained by assuming C , symmetry. They can be described as arising from linear combinations between the 3p lone-pair at sulfur and 2p lone-pairs at the oxygen atoms. A comparison between the

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