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The photoelectron spectra of D2d and C2ν hydrocarbons containing two norbornadiene or quadricylane groups

✍ Scribed by Branka Kovač; Edgar Heilbronner; Horst Prinzbach; Klaus Weidmann

Publisher: John Wiley and Sons
Year: 1979
Tongue: German
Weight: 633 KB
Volume: 62
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.19790620835

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✦ Synopsis

Abstract

The photoelectron spectra of the hydrocarbons 1 to 4 have been recorded and interpreted by qualitative correlation with the spectra of their subsystems norbornadiene, quadricyclane, allene and cyclopropane.

It has been shown that the interactions of the symmetry adapted orbitals of the subsystems are governed not only by their symmetry behaviour with respect to D~2__d__~ in 1 and 2, or C~2ν~ in 3 and 4, but also by the local symmetry at the points of attachment of the subsystems.

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