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The photodegradation of poly(vinyl chloride)—V The effect of wavelength of irradiation on the dehydrochlorination reaction

✍ Scribed by W.H. Gibb; J.R. MacCallum

Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
263 KB
Volume
10
Category
Article
ISSN
0014-3057

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✦ Synopsis

For a purified sample of poly(vinyl chloride), it is found that radiation of wavelength less than 300 nm causes dehydrochlorination. It appears that polychromatic radiation yields a constant ratio of concentrations of polyenes, even from the very early stages of reaction. It is proposed that energy transfer is an important step in the photodecomposition of poly(vinyl chloride).

Previous papers in this series have dealt with various

o.e aspects of the photochemically induced decomposition of poly(vinyl chloride) [1][2][3][4]. In this paper, the effects 0.7 of varying the wavelengths of incident radiation are in-, vestigated.

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