✦ LIBER ✦

The photochlorination of perfluorocyclopentene

✍ Scribed by Z. R. Alberto; J. J. Cosa; E. H. Staricco

Publisher: John Wiley and Sons
Year: 1973
Tongue: English
Weight: 332 KB
Volume: 5
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550050302

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The gas‐phase photochlorination of perfluorocyclopentene under continuous and intermittent illumination with 4360‐Å radiation was studied between 10° and 60°C. The rate constants for the reactions. (3)
(4)
were measured as k~3~ = (1.20 + 0.58) × 10^8^ exp (−6.430 ± 177/RT) l·(mole sec) and k~4~ = (1.86 ± 0.76) × 10^7^ l·(mole sec).

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