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The Photochlorination of 2-Methylpropane-2-d and α-d 1 -Toluene; the Question of Free Radical Rearrangement or Exchange in Substitution Reactions 1,2

✍ Scribed by Brown, Herbert C.; Russell, Glen A.

Book ID: 121273464
Publisher: American Chemical Society
Year: 1952
Tongue: English
Weight: 545 KB
Volume: 74
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja01136a007

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## Abstract Rate coefficients, __k__, and ClO radical product yields, __Y__, for the gas‐phase reaction of O(^1^D) with CClF~2~CCl~2~F (CFC‐113) (__k__~2~), CCl~3~CF~3~ (CFC‐113a) (__k__~3~), CClF~2~CClF~2~ (CFC‐114) (__k__~4~), and CCl~2~FCF~3~ (CFC‐114a) (__k__~5~) at 296 K are reported. Rate coe