The photochemistry of hexafluoroacetylacetone in the vapour phase. Occurrence of a novel HF elimination reaction

✍ Scribed by John E. Bassett; Eric Whittle

• Book ID: 102928591
• Publisher: John Wiley and Sons
• Year: 1976
• Tongue: English
• Weight: 782 KB
• Volume: 8
• Category: Article
• ISSN: 0538-8066
• DOI: 10.1002/kin.550080606

✦ Synopsis

Photolysis of the vapour of hexafluoroacetylacetone HFAA in its enolic form involves decomposition by two independent primary processes, one of which is a novel elimination of H F giving 2,2-difluoro-2,3-dihydro-5trifluoromethylfuran-3-one:

cmsx(l./mole . cm