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The photochemistry of C10Cl8O2, m.p. 190°. A stereochemical structure reassignment

✍ Scribed by Albert Padwa; Joseph Masaracchia; Victor Mark

Book ID: 104248046
Publisher: Elsevier Science
Year: 1971
Tongue: French
Weight: 182 KB
Volume: 12
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)97119-9

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✦ Synopsis

A pair of Cl0 Cl 0 diketones [(A) m-p. 8 2 190° and (2) m.p. 2EO"] has been described by P. E. Eaton for which, based on their spectral and chemical behavior, . the structural framework of A or B has been tentatively proposed.' Subseguently Scribner, who obtained the same diketones by alternate reactions, ascribed, tentatively again, the cis,anti,cis stereochemical structures C and D to (A)

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