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The Photochemistry of 4,5-Carbomethoxy-1,2,3-thiadiazole: Direct Observation of Thiirene Formation and Its Decay in Solution

✍ Scribed by Burdzinski, Gotard; Luk, Hoi Ling; Reid, Carolyn S.; Zhang, Yunlong; Hadad, Christopher M.; Platz, Matthew S.


Book ID
120358876
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
781 KB
Volume
117
Category
Article
ISSN
1089-5639

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Ah&met-The equilibrium between I and the product restthing from the addition of ethanol to one of its C-N double bonds: 3-ethoxy-3,4-diphenyl-lJ,Qhiadisxohne 1,ldioxide (II), is studied by electrochemical methods in ethanol (EtOH)-acetonitrile (ACN) solvent mixtures. The equilibrium constant is meas