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The photochemical synthesis of a tricyclo[2.2.0.02,5]hexane

โœ Scribed by Alexander, Edward C.; Uliana, Joseph


Book ID
120366957
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
248 KB
Volume
98
Category
Article
ISSN
0002-7863

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Photochemical synthesis of a 2,5-dioxabi
โœ J.Christopher Dalton; Samuel J. Tremont ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 196 KB

We report that irradiation of 3-methyl-4-oxa-5-hexen-2-one, 1,, yields al,&dimethyl-2,5-dioxabicyclo[2.2.O]hexane, 2, the first 2,5-dicxabicycLo[2.2.0]hexane to be reported.' 1, was prepared in 39s yield2 by a transetherification reactions between 3hydroxy-2-butanone and methyl vinyl ether (eqn. 1).